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结构玻璃中的粒子跳跃。

Particle jumps in structural glasses.

作者信息

Ciamarra Massimo Pica, Pastore Raffaele, Coniglio Antonio

机构信息

Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore and CNR-SPIN, Dipartimento di Scienze Fisiche, University of Napoli Federico II, Italy.

CNR-SPIN, Dipartimento di Scienze Fisiche, University of Napoli Federico II, Italy.

出版信息

Soft Matter. 2016 Jan 14;12(2):358-66. doi: 10.1039/c5sm01568e.

Abstract

Particles in structural glasses rattle around temporary equilibrium positions, that seldom change through a process which is much faster than the relaxation time, known as particle jump. Since the relaxation of the system is due to the accumulation of many such jumps, it could be possible to connect the single particle short time motion to the macroscopic relaxation by understanding the features of the jump dynamics. Here we review recent results in this research direction, clarifying the features of particle jumps that have been understood and those that are still under investigation, and examining the role of particle jumps in different theories of the glass transition.

摘要

结构玻璃中的粒子在临时平衡位置附近振动,这些位置很少通过一个比弛豫时间快得多的过程发生变化,这个过程称为粒子跳跃。由于系统的弛豫是由于许多此类跳跃的积累,通过理解跳跃动力学的特征,有可能将单个粒子的短时间运动与宏观弛豫联系起来。在这里,我们回顾了这个研究方向的最新成果,阐明了已经理解的粒子跳跃特征和仍在研究中的特征,并考察了粒子跳跃在不同玻璃化转变理论中的作用。

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