Férey Gérard
Académie des Sciences & Institut Lavoisier, Université de Versailles, 45, Avenue des Etats-Unis, 78035, Versailles Cedex, France.
Dalton Trans. 2016 Mar 14;45(10):4073-89. doi: 10.1039/c5dt03547c.
The large reversible flexibility of hybrid crystallized matter is relatively new. After briefly recalling the history of this discovery, the article will analyze the different parameters influencing this phenomenon. They relate first to the various structural characteristics of the framework, in both its inorganic and organic parts. The influence of the energies of the guest-guest and host-guest interactions is then analyzed. Once the reasons are explained, a third section will be devoted to the various physical properties of these flexible solids. The last section concerns recent industrial applications of this family of solids.
混合结晶物质具有的较大可逆柔韧性相对较新。在简要回顾这一发现的历史之后，本文将分析影响这一现象的不同参数。这些参数首先涉及框架在无机和有机部分的各种结构特征。接着分析客体 - 客体和主体 - 客体相互作用能量的影响。解释完原因后，第三部分将专门探讨这些柔性固体的各种物理性质。最后一部分涉及这类固体最近的工业应用。
