由巨型 [Pb(II)18I54(I2)9] 轮簇构建的半导体纳米管阵列。
Semiconductive Nanotube Array Constructed from Giant [Pb(II)18I54(I2)9] Wheel Clusters.
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao west road 155#, Fuzhou, Fujian 350002 (China).
出版信息
Angew Chem Int Ed Engl. 2016 Jan 11;55(2):514-8. doi: 10.1002/anie.201507083. Epub 2015 Nov 9.
Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [Pb(II)18I54(I2)9] wheel cluster, as determined by synchrotron X-ray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semiconductivity and highly anisotropic conductivity.
晶状纳米管阵列将为新型电气应用创造巨大机会。在此，我们报告首例基于金属卤化物的晶状纳米管阵列，其由前所未有的巨型[Pb(II)18I54(I2)9]轮簇构建，这是通过同步加速器 X 射线衍射确定的。对单晶的电学性能进行了研究，本化合物表现出典型的半导体和各向异性导电性。
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