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基于氧化锰的化学动力微型马达。

Manganese Oxide-Based Chemically Powered Micromotors.

机构信息

Department of Chemistry, University of Eastern Finland , FI-80101 Joensuu, Finland.

出版信息

ACS Appl Mater Interfaces. 2015 Nov 25;7(46):25580-5. doi: 10.1021/acsami.5b08789. Epub 2015 Nov 10.

Abstract

Chemically powered micromotors represent an exciting research area in nanotechnology. Such artificial devices are typically driven by catalytic bubble formation, taking place at the solid-liquid interface. Platinum has been most frequently used for the fabrication of different micromotors due to its superior catalytic efficiency. Other materials typically suffer from slow speeds and require very high concentrations of chemical fuel. Here, we report preparation and characterization of fast moving micromotors based on manganese oxide (MnO2) with different geometrical shapes (tubes, rods, and spheres). On the basis of the results, the prepared micromotors reached the highest speeds (up to ∼900 μm s(-1) in 10% H2O2) reported to date for any MnO2-based micromotors. Moreover, they moved by bubble propulsion even at very low concentrations of peroxide fuel. Thus, MnO2 represents a promising material for the preparation of micromotors for various biomedical or environmental applications, where high speeds are desired.

摘要

化学动力微型马达是纳米技术中一个令人兴奋的研究领域。这种人工设备通常是通过在固液界面处发生的催化气泡形成来驱动的。由于其催化效率高,铂最常用于制造不同的微型马达。其他材料通常速度较慢,并且需要非常高浓度的化学燃料。在这里,我们报告了基于二氧化锰 (MnO2) 的不同几何形状(管、棒和球)的快速运动微型马达的制备和表征。根据结果,所制备的微型马达达到了迄今为止报道的任何基于 MnO2 的微型马达的最高速度(在 10% H2O2 中高达约 900 μm s(-1))。此外,即使在过氧化物燃料的浓度非常低的情况下,它们也可以通过气泡推进来移动。因此,MnO2 是制备各种生物医学或环境应用的微型马达的有前途的材料,在这些应用中需要高速。

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