Yang Shuangqiao, Bai Shibing, Wang Qi
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China.
State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, China.
Waste Manag. 2016 Nov;57:168-175. doi: 10.1016/j.wasman.2015.11.005. Epub 2015 Nov 6.
In this study nonmetals recycled from waste printed circuit boards (NPCB) is used as reinforce fillers in high-density polyethylene (HDPE) composites. The morphology, mechanical and thermal oxidative aging properties of NPCB reinforced HDPE composites are assessed and it compared with two other commercial functional filler for the first time. Mechanical test results showed that NPCB could be used as reinforcing fillers in the HDPE composites and mechanical properties especially for stiffness is better than other two commercial fillers. The improved mechanical property was confirmed by the higher aspect ratio and strong interfacial adhesion in scanning electron microscopy (SEM) studies. The heat deflection temperature (HDT) test showed the presence of fiberglass in NPCB can improve the heat resistance of composite for their potential applications. Meanwhile, the oxidation induction time (OIT) and the Fourier transform infrared (FTIR) spectroscopy results showed that NPCB has a near resistance to oxidation as two other commercial fillers used in this paper. The above results show the reuse of NPCB in the HDPE composites represents a promising way for resolving both the environmental pollution and the high-value reuse of resources.
在本研究中,从废印刷电路板中回收的非金属(NPCB)被用作高密度聚乙烯(HDPE)复合材料的增强填料。首次评估了NPCB增强HDPE复合材料的形态、力学和热氧化老化性能,并将其与另外两种商业功能填料进行了比较。力学测试结果表明,NPCB可用作HDPE复合材料的增强填料,其力学性能,尤其是刚度,优于其他两种商业填料。扫描电子显微镜(SEM)研究中较高的长径比和较强的界面附着力证实了力学性能的改善。热变形温度(HDT)测试表明,NPCB中玻璃纤维的存在因其潜在应用可提高复合材料的耐热性。同时,氧化诱导时间(OIT)和傅里叶变换红外(FTIR)光谱结果表明,NPCB与本文使用的其他两种商业填料具有相近的抗氧化性。上述结果表明,NPCB在HDPE复合材料中的再利用是解决环境污染和资源高价值再利用的一条有前景的途径。