Liu Shu-Xun, Yang Hang-Yu, Li Si-Yu, Zhang Jia-Yue, Li Teng, Zhu Bao-Qing, Zhang Bo-Lin
Beijing Key Laboratory of Forestry Food Processing and Safety, Department of Food science, College of Biological Sciences and Biotechnology, Beijing Forestry University, Beijing 10083, China.
Center for Viticulture and Enology, College of Food Science & Nutritional Engineering, China Agricultural University, Beijing 100083, China.
Molecules. 2015 Nov 4;20(11):19865-77. doi: 10.3390/molecules201119662.
Phenolic compounds determine the color quality of fruit wines. In this study, the phenolic compound content and composition, color characteristics and changes during 6 months of bottle aging were studied in wines fermented with bog bilberry syrup under three different pHs. The total anthocyanins and total phenols were around 15.12-16.23 mg/L and 475.82 to 486.50 mg GAE/L in fresh wines and declined 22%-31% and about 11% in bottle aged wines, respectively. In fresh wines, eight anthocyanins, six phenolic aids and 14 flavonols, but no flavon-3-ols were identified; Malvidin-3-O-glucoside, petunidin-3-O-glucoside and delphinium-3-O-glucoside were the predominant pigments; Chlorogentic acid was the most abundant phenolic acid, and quercetin-3-O-galactoside and myricetin-3-O-galactoside accounted for nearly 90% of the total flavonols. During 6 months of bottle storage, the amounts of all the monomeric anthocyanins and phenolic acids were reduced dramatically, while the glycosidyl flavonols remained constant or were less reduced and their corresponding aglycones increased a lot. The effects of aging on blueberry wine color were described as the loss of color intensity with a dramatic change in color hue, from initial red-purple up to final red-brick nuances, while the pH of the fermentation matrix was negatively related to the color stability of aged wine.
酚类化合物决定了果酒的色泽品质。本研究对三种不同pH值下用笃斯越桔糖浆发酵的葡萄酒在瓶中陈酿6个月期间的酚类化合物含量与组成、颜色特征及变化进行了研究。新鲜葡萄酒中的总花色苷和总酚分别约为15.12 - 16.23 mg/L和475.82至486.50 mg GAE/L,瓶陈葡萄酒中分别下降了22% - 31%和约11%。在新鲜葡萄酒中,鉴定出了8种花色素苷、6种酚酸和14种黄酮醇,但未鉴定出黄酮 - 3 - 醇;矢车菊素 - 3 - O - 葡萄糖苷、矮牵牛素 - 3 - O - 葡萄糖苷和飞燕草素 - 3 - O - 葡萄糖苷是主要色素;绿原酸是含量最丰富的酚酸,槲皮素 - 3 - O - 半乳糖苷和杨梅素 - 3 - O - 半乳糖苷占总黄酮醇的近90%。在瓶贮6个月期间,所有单体花色苷和酚酸的含量均大幅降低,而糖苷基黄酮醇含量保持不变或降低较少,其相应的苷元大量增加。陈酿对蓝莓酒颜色的影响表现为颜色强度降低,颜色色调发生显著变化,从最初的红紫色变为最终的红砖色,而发酵基质的pH值与陈酿葡萄酒的颜色稳定性呈负相关。