通过末端炔烃和双(频哪醇)硼酸酯之间的布朗斯特碱催化反应合成 1,1-二硼烯。
Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
机构信息
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810 (Japan) http://wwwchem.sci.hokudai.ac.jp/∼orgmet/index.php.
出版信息
Angew Chem Int Ed Engl. 2015 Dec 21;54(52):15859-62. doi: 10.1002/anie.201509218. Epub 2015 Nov 13.
PMID:26564784
Abstract
A method for the synthesis of 1,1-diborylalkenes through a Brønsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1-diborylalkenes from various terminal alkynes including propiolates, propiolamides, and 2-ethynylazoles.
摘要
一种通过末端炔烃与双(频哪醇)二硼之间的 Brønsted 碱催化反应合成 1,1-二硼烯的方法已经被开发出来。该方法允许从各种末端炔烃（包括丙炔酸酯、丙炔酰胺和 2-乙炔基唑）直接合成官能化的 1,1-二硼烯。
Zotero 插件