在聚（L-多巴）功能化衬底上进行同手性金属有机框架薄膜的液相外延生长以改善对映体分离。
Liquid-phase epitaxial growth of a homochiral MOF thin film on poly(L-DOPA) functionalized substrate for improved enantiomer separation.
作者信息
Gu Zhi-Gang, Fu Wen-Qiang, Wu Xin, Zhang Jian
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou, P. R. China.
出版信息
Chem Commun (Camb). 2016 Jan 14;52(4):772-5. doi: 10.1039/c5cc07614e.
A homochiral MOF film grown on a functionalized substrate in a capillary column with high orientation and homogeneity was successfully prepared by using a layer-by-layer liquid phase epitaxial method; by introducing self-polymerized 3,4-dihydroxy-L-phenylalanine (poly(L-DOPA)) as a chiral substrate, the obtained enantiopure substrate mounted homochiral MOF thin film showed improved enantiomer separation.
通过逐层液相外延法，成功地在具有高取向性和均匀性的毛细管柱中的功能化基底上制备了一种具有同手性的金属有机框架（MOF）薄膜；通过引入自聚合的3,4-二羟基-L-苯丙氨酸（聚（L-DOPA））作为手性基底，所获得的安装有同手性MOF薄膜的对映体纯基底表现出改善的对映体分离性能。
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