• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一种包含轴向键合金属卟啉的电聚合晶体薄膜：基于钌（II/III）的电致变色具有显著的可逆性、可重复性和着色效率。

An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism.

作者信息

Abe Masaaki, Futagawa Hiroki, Ono Toshikazu, Yamada Teppei, Kimizuka Nobuo, Hisaeda Yoshio

机构信息

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University , 744, Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan.

Center for Molecular Systems (CMS), Kyushu University , 744, Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan.

出版信息

Inorg Chem. 2015 Dec 7;54(23):11061-3. doi: 10.1021/acs.inorgchem.5b02129. Epub 2015 Nov 16.

DOI:10.1021/acs.inorgchem.5b02129
PMID:26569481
Abstract

Oxidative electropolymeization of an axially bound, bithiophene-pyridine complex of ruthenium(III)-porphycene [Ru(TPrPc) (btp)2]PF6 (1) gives a submicrometer-thick, polymeric film on an ITO electrode with a crystalline morphology. The polymeric film, the first example of axially linked multimetalloporphycene coordination arrays, exhibits highly stable and reproducible electrochromic response with high electrochromic efficiency upon electrochemical control over the metal-centered electron transfer process (Ru(II)/Ru(III)).

摘要

钌（III）-卟啉[Ru（TPrPc）（btp）2]PF6（1）的轴向结合的联二噻吩-吡啶配合物的氧化电聚合在ITO电极上形成了具有晶体形态的亚微米厚聚合物膜。该聚合物膜是轴向连接的多金属卟啉配位阵列的首个实例，在对以金属为中心的电子转移过程（Ru（II）/Ru（III））进行电化学控制时，表现出高度稳定且可重现的电致变色响应，且电致变色效率高。

相似文献

1
An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism.一种包含轴向键合金属卟啉的电聚合晶体薄膜：基于钌（II/III）的电致变色具有显著的可逆性、可重复性和着色效率。
Inorg Chem. 2015 Dec 7;54(23):11061-3. doi: 10.1021/acs.inorgchem.5b02129. Epub 2015 Nov 16.
2
Reductive electropolymerization of bis-tridentate ruthenium complexes with 5,5''-divinyl-4'-tolyl-2,2':6',2''-terpyridine.双齿钌配合物与 5,5''-二乙烯基-4'-甲苯基-2,2':6',2''-三联吡啶的还原电化学聚合。
Dalton Trans. 2013 Oct 21;42(39):14125-33. doi: 10.1039/c3dt51627j.
3
Near-infrared electrochromism in electropolymerized metallopolymeric films of a phen-1,4-diyl-bridged diruthenium complex.苯-1,4-二亚基桥连二钌配合物的电聚合金属聚合物薄膜中的近红外电致变色现象
Inorg Chem. 2014 Oct 20;53(20):11316-22. doi: 10.1021/ic5019967. Epub 2014 Oct 9.
4
Synthesis, electrochemical, and molecular inclusion properties of 'canopied' trinuclear ruthenium complexes with six anchoring groups on an ITO electrode.在ITO电极上具有六个锚定基团的“带顶篷”三核钌配合物的合成、电化学及分子包合性质
Dalton Trans. 2008 Sep 28(36):4846-54. doi: 10.1039/b807526c. Epub 2008 Aug 18.
5
Mechanistic Insights into Anion-Induced Electrochromism of Ru(II)-Based Metallo-Supramolecular Polymer.基于钌（II）的金属超分子聚合物中阴离子诱导电致变色的机理研究
Polymers (Basel). 2023 Dec 18;15(24):4735. doi: 10.3390/polym15244735.
6
Electrochemistry and Electrochromic Performance of a Metallopolymer Formed by Electropolymerization of a Fe(II) Complex with a Triphenylamine-Hydrazone Ligand.由含三苯胺-腙配体的Fe(II)配合物电聚合形成的金属聚合物的电化学与电致变色性能
Chemphyschem. 2022 Feb 16;23(4):e202100780. doi: 10.1002/cphc.202100780. Epub 2022 Jan 18.
7
First example of mu(3)-sulfido bridged mixed-valent triruthenium complex triangle Ru(III)(2)Ru(II)(O,O-acetylacetonate)(3)(mu-O,O,gamma-C-acetylacetonate)(3)(mu(3)-S) (1) incorporating simultaneous O,O- and gamma-C-bonded bridging acetylacetonate units. Synthesis, crystal structure, and spectral and redox properties.首例含同时通过O,O-和γ-C键桥连乙酰丙酮单元的μ(3)-硫桥连混合价态三钌配合物三角Ru(III)₂Ru(II)(O,O-乙酰丙酮)(3)(μ-O,O,γ-C-乙酰丙酮)(3)(μ(3)-S) (1)。合成、晶体结构以及光谱和氧化还原性质。
Inorg Chem. 2003 Feb 24;42(4):1322-7. doi: 10.1021/ic026221i.
8
Synthesis, luminescence, and electrochemical studies of tris(homoleptic) ruthenium(II) and osmium(II) complexes of 6'-tolyl-2,2':4',2''-terpyridine.6'-甲苯基-2,2':4',2''-三联吡啶的三（均配体）钌（II）和锇（II）配合物的合成、发光及电化学研究
Inorg Chem. 2007 Aug 6;46(16):6252-60. doi: 10.1021/ic0700093. Epub 2007 Jul 11.
9
Electrochromic hysteresis performance of a prussian blue film arising from electron-transfer control by a tris(2,2'-bipyridine)ruthenium(II)-doped WO(3) film as studied by a spectrocyclic voltammetry technique.通过光谱循环伏安法技术研究三（2,2'-联吡啶）钌（II）掺杂的WO(3)薄膜对电子转移的控制作用所引起的普鲁士蓝薄膜的电致变色滞后性能。
Chemistry. 2006 Nov 15;12(33):8558-65. doi: 10.1002/chem.200600369.
10
Electroswitching of emission and coloration with quick response and high reversibility in an electrochemical cell.电化学池中的快速响应和高可逆性的电致变色和发射的电切换。
Chem Asian J. 2012 Nov;7(11):2551-4. doi: 10.1002/asia.201200731. Epub 2012 Sep 14.

引用本文的文献

1
Gram-scale synthesis of porphycenes through acid-catalyzed oxidative macrocyclizations of /-mixed 5,6-diaryldipyrroethenes.通过酸催化的/-混合5,6-二芳基二吡咯乙烯的氧化大环化反应进行克级卟吩的合成。
RSC Adv. 2018 Nov 26;8(69):39269-39273. doi: 10.1039/c8ra09040h. eCollection 2018 Nov 23.
2
Reductive Electropolymerization and Electrochromism of Iron(II) Complex with Styrene-Based Ligand.基于苯乙烯配体的铁（II）配合物的还原电聚合及电致变色性能
Materials (Basel). 2021 Aug 25;14(17):4831. doi: 10.3390/ma14174831.
3
2 + 2 Can Make Nearly a Thousand! Comparison of Di- and Tetra--Alkyl-Substituted Porphycenes.
2 + 2 几乎能得出一千！二烷基和四烷基取代卟啉的比较。
J Phys Chem A. 2020 Jun 11;124(23):4594-4604. doi: 10.1021/acs.jpca.0c02155. Epub 2020 May 28.