Nasrollahzadeh Mahmoud, Sajadi S Mohammad
Department of Chemistry, Faculty of Science, University of Qom, P.O. Box 37185-359, Qom, Iran.
Department of Petroleum Geoscience, Faculty of Science, Soran University, PO Box 624, Soran, Kurdistan Regional Government, Iraq.
J Colloid Interface Sci. 2016 Feb 15;464:147-52. doi: 10.1016/j.jcis.2015.11.020. Epub 2015 Nov 11.
We describe a method for supporting palladium nanoparticles on magnetic nanoparticles using Euphorbia stracheyi Boiss root extract as the natural source of reducing and stabilizing agent. The progress of the reaction was monitored using UV-visible spectroscopy. The nanocatalyst was characterized by FE-SEM, TEM, XRD, EDS, FT-IR spectroscopy and ICP. The nanocatalyst was applied as an efficient, magnetically recoverable, highly reusable and heterogeneous catalyst for one-pot reductive amination of aldehydes at room temperature. The nanocatalyst was easily recovered by applying an external magnet and reused several times without considerable loss of activity.
我们描述了一种使用大戟科植物(Euphorbia stracheyi Boiss)根提取物作为还原和稳定剂的天然来源,在磁性纳米颗粒上负载钯纳米颗粒的方法。使用紫外可见光谱监测反应进程。通过场发射扫描电子显微镜(FE-SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、能谱仪(EDS)、傅里叶变换红外光谱(FT-IR)和电感耦合等离子体质谱(ICP)对纳米催化剂进行了表征。该纳米催化剂被用作一种高效、可磁回收、高度可重复使用的多相催化剂,用于在室温下一锅法进行醛的还原胺化反应。通过施加外部磁场可轻松回收该纳米催化剂,并且可以重复使用多次而活性没有明显损失。