• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

脂肪酸、脂肪酸酯和植物油的化学酶促环氧化技术综述

Technological Aspects of Chemoenzymatic Epoxidation of Fatty Acids, Fatty Acid Esters and Vegetable Oils: A Review.

作者信息

Milchert Eugeniusz, Malarczyk Kornelia, Kłos Marlena

机构信息

Institute of Organic Chemical Technology, Faculty of Chemical Engineering, West Pomeranian University of Technology Szczecin, 10 Pulaski St., 70-322 Szczecin, Poland.

出版信息

Molecules. 2015 Dec 2;20(12):21481-93. doi: 10.3390/molecules201219778.

DOI:10.3390/molecules201219778
PMID:26633342
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6332370/
Abstract

The general subject of the review is analysis of the effect of technological parameters on the chemoenzymatic epoxidation processes of vegetable oils, fatty acids and alkyl esters of fatty acids. The technological parameters considered include temperature, concentration, amount of hydrogen peroxide relative to the number of unsaturated bonds, the amounts of enzyme catalysts, presence of solvent and amount of free fatty acids. Also chemical reactions accompanying the technological processes are discussed together with different technological options and significance of the products obtained.

摘要

该综述的总体主题是分析工艺参数对植物油、脂肪酸和脂肪酸烷基酯的化学酶促环氧化过程的影响。所考虑的工艺参数包括温度、浓度、相对于不饱和键数量的过氧化氢量、酶催化剂的用量、溶剂的存在以及游离脂肪酸的量。同时,还讨论了工艺过程中伴随的化学反应以及不同的工艺选择和所得产物的意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/ba50478809e4/molecules-20-19778-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/2049dcc318dc/molecules-20-19778-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/dd0e13fdfb86/molecules-20-19778-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/bf872968cb08/molecules-20-19778-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/ba50478809e4/molecules-20-19778-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/2049dcc318dc/molecules-20-19778-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/dd0e13fdfb86/molecules-20-19778-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/bf872968cb08/molecules-20-19778-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee0/6332370/ba50478809e4/molecules-20-19778-g004.jpg

相似文献

1
Technological Aspects of Chemoenzymatic Epoxidation of Fatty Acids, Fatty Acid Esters and Vegetable Oils: A Review.脂肪酸、脂肪酸酯和植物油的化学酶促环氧化技术综述
Molecules. 2015 Dec 2;20(12):21481-93. doi: 10.3390/molecules201219778.
2
Epoxidation of Methyl Esters as Valuable Biomolecules: Monitoring of Reaction.甲酯的环氧化作为有价值的生物分子:反应监测。
Molecules. 2023 Mar 21;28(6):2819. doi: 10.3390/molecules28062819.
3
Biocatalytic acylation of carbohydrates with fatty acids from palm fatty acid distillates.利用棕榈脂肪酸蒸馏物中的脂肪酸对碳水化合物进行生物催化酰化反应。
J Ind Microbiol Biotechnol. 2006 May;33(5):338-42. doi: 10.1007/s10295-005-0073-0. Epub 2006 Jan 10.
4
Enzymatic esterification of free fatty acids in vegetable oils utilizing different immobilized lipases.利用不同固定化脂肪酶对植物油中的游离脂肪酸进行酶促酯化反应。
Biotechnol Lett. 2015 Jan;37(1):169-74. doi: 10.1007/s10529-014-1668-1. Epub 2014 Sep 12.
5
Reaction pathways for the deoxygenation of vegetable oils and related model compounds.植物油及相关模型化合物脱氧的反应途径。
ChemSusChem. 2013 Sep;6(9):1576-94. doi: 10.1002/cssc.201300370. Epub 2013 Aug 1.
6
Ultrasonic versus silent methylation of vegetable oils.植物油的超声甲基化与无声甲基化
Ultrason Sonochem. 2006 Jul;13(5):401-7. doi: 10.1016/j.ultsonch.2005.08.001. Epub 2005 Oct 19.
7
Lipase catalyzed epoxidation of fatty acid methyl esters derived from unsaturated vegetable oils in absence of carboxylic acid.脂肪酶在无羧酸存在的情况下催化源自不饱和植物油的脂肪酸甲酯的环氧化反应。
Chem Cent J. 2018 Apr 11;12(1):39. doi: 10.1186/s13065-018-0409-2.
8
Preparation of Fatty Acid and Monoglyceride from Vegetable Oil.从植物油制备脂肪酸和甘油单酯。
J Oleo Sci. 2020;69(4):277-295. doi: 10.5650/jos.ess19168.
9
Toxicological assessment of 3-chloropropane-1,2-diol and glycidol fatty acid esters in food.食品中 3-氯-1,2-丙二醇和缩水甘油脂肪酸酯的毒理学评估。
Mol Nutr Food Res. 2011 Apr;55(4):509-21. doi: 10.1002/mnfr.201000550. Epub 2011 Feb 23.
10
Pilot-scale production of biodiesel from waste fats and oils using tetramethylammonium hydroxide.用四甲氢氧化铵从废弃油脂中大规模生产生物柴油。
Waste Manag. 2016 Feb;48:630-637. doi: 10.1016/j.wasman.2015.10.005. Epub 2015 Oct 12.

引用本文的文献

1
Fluorescence Lifetime of Chlorophyll α in Oxidized Edible Vegetable Oil.叶绿素 α 在氧化食用植物油中的荧光寿命。
J Fluoresc. 2024 Jul;34(4):1841-1849. doi: 10.1007/s10895-023-03415-9. Epub 2023 Aug 30.
2
Enzymatic and Synthetic Routes of Castor Oil Epoxidation.蓖麻油环氧化的酶促和合成路线。
Polymers (Basel). 2023 May 27;15(11):2477. doi: 10.3390/polym15112477.
3
Synthesis of Bio-Based Thermoset Mixture Composed of Methacrylated Rapeseed Oil and Methacrylated Methyl Lactate: One-Pot Synthesis Using Formed Methacrylic Acid as a Continual Reactant.

本文引用的文献

1
Lubricants from chemically modified vegetable oils.来自化学改性植物油的润滑剂。
Bioresour Technol. 2010 Jan;101(1):245-54. doi: 10.1016/j.biortech.2009.08.035. Epub 2009 Aug 28.
2
Epoxidation of cottonseed oil by aqueous hydrogen peroxide catalysed by liquid inorganic acids.液态无机酸催化过氧化氢水溶液对棉籽油进行环氧化反应。
Bioresour Technol. 2008 Jun;99(9):3737-44. doi: 10.1016/j.biortech.2007.07.015. Epub 2007 Aug 30.
3
Lipases in lipophilization reactions.亲脂化反应中的脂肪酶。
由甲基丙烯酸化菜籽油和甲基丙烯酸化乳酸甲酯组成的生物基热固性混合物的合成:使用生成的甲基丙烯酸作为连续反应物的一锅法合成
Polymers (Basel). 2023 Apr 7;15(8):1811. doi: 10.3390/polym15081811.
4
Aquivion perfluorosulfonic superacid as an effective catalyst for selective epoxidation of vegetable oils.阿奎维翁全氟磺酸超酸作为植物油选择性环氧化的有效催化剂。
R Soc Open Sci. 2022 Apr 27;9(4):211554. doi: 10.1098/rsos.211554. eCollection 2022 Apr.
5
Catalytic developments in the epoxidation of vegetable oils and the analysis methods of epoxidized products.植物油环氧化反应的催化进展及环氧化产物的分析方法
RSC Adv. 2019 Nov 21;9(65):38119-38136. doi: 10.1039/c9ra05943a. eCollection 2019 Nov 19.
6
Sustainable access to fully biobased epoxidized vegetable oil thermoset materials prepared by thermal or UV-cationic processes.通过热法或紫外光阳离子法制备的全生物基环氧化植物油热固性材料的可持续获取。
RSC Adv. 2020 Nov 18;10(68):41954-41966. doi: 10.1039/d0ra07682a. eCollection 2020 Nov 11.
7
Room-temperature production of bio-based aldehydes from vegetable oil-derived epoxide HWO@Al-MCM-41 as recyclable catalyst.以植物油衍生的环氧化物HWO@Al-MCM-41作为可循环催化剂在室温下制备生物基醛类
RSC Adv. 2019 Jul 25;9(40):23061-23070. doi: 10.1039/c9ra04348a. eCollection 2019 Jul 23.
8
Oxidative Stability of Vegetal Oil-Based Lubricants.植物油基润滑剂的氧化稳定性
ACS Sustain Chem Eng. 2021 Feb 1;9(4):1459-1476. doi: 10.1021/acssuschemeng.0c06988. Epub 2021 Jan 19.
9
Fatty Acids and their Derivatives as Renewable Platform Molecules for the Chemical Industry.脂肪酸及其衍生物作为化学工业的可再生平台分子。
Angew Chem Int Ed Engl. 2021 Sep 6;60(37):20144-20165. doi: 10.1002/anie.202100778. Epub 2021 May 1.
10
Conversion of Oleic Acid into Azelaic and Pelargonic Acid by a Chemo-Enzymatic Route.通过化学-酶法将油酸转化为壬二酸和庚二酸。
Molecules. 2020 Apr 18;25(8):1882. doi: 10.3390/molecules25081882.
Biotechnol Adv. 2007 Nov-Dec;25(6):515-36. doi: 10.1016/j.biotechadv.2007.06.001. Epub 2007 Jul 10.
4
Lipids as renewable resources: current state of chemical and biotechnological conversion and diversification.脂质作为可再生资源:化学与生物技术转化及多样化的现状
Appl Microbiol Biotechnol. 2006 Jun;71(1):13-22. doi: 10.1007/s00253-006-0335-4. Epub 2006 Apr 8.
5
Synthesis of diethylamine-functionalized soybean oil.二乙胺官能化大豆油的合成
J Agric Food Chem. 2005 Nov 30;53(24):9485-90. doi: 10.1021/jf050731o.
6
Studies on the epoxidation of mahua oil (Madhumica indica) by hydrogen peroxide.过氧化氢对麻疯树油(麻疯树)进行环氧化反应的研究。
Bioresour Technol. 2006 Aug;97(12):1365-71. doi: 10.1016/j.biortech.2005.07.004. Epub 2005 Aug 24.
7
European survey of contamination of homogenized baby food by epoxidized soybean oil migration from plasticized PVC gaskets.欧洲关于增塑聚氯乙烯垫片中环氧大豆油迁移对均质婴儿食品污染情况的调查。
Food Addit Contam. 2003 Nov;20(11):1087-96. doi: 10.1080/02652030310001615186.
8
New Syntheses with Oils and Fats as Renewable Raw Materials for the Chemical Industry.以油脂作为化学工业可再生原料的新合成方法。
Angew Chem Int Ed Engl. 2000 Jul 3;39(13):2206-2224. doi: 10.1002/1521-3773(20000703)39:13<2206::aid-anie2206>3.0.co;2-p.
9
The sequence, crystal structure determination and refinement of two crystal forms of lipase B from Candida antarctica.南极假丝酵母脂肪酶B两种晶体形式的序列、晶体结构测定与精修
Structure. 1994 Apr 15;2(4):293-308. doi: 10.1016/s0969-2126(00)00031-9.
10
Factors influencing ester synthesis catalysed in aqueous media by the lipase from Candida deformans (Zach) Langeron and Guerra.
J Biotechnol. 1995 Aug 15;42(1):23-33. doi: 10.1016/0168-1656(95)00060-4.