Kottrup Konstantin G, Hetterscheid Dennis G H
Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.
Chem Commun (Camb). 2016 Feb 11;52(12):2643-6. doi: 10.1039/c5cc10092e. Epub 2016 Jan 11.
Using on-line mass spectrometry in combination with classical electroanalytical techniques makes it possible to reliably determine onset potentials and to distinguish between competing reactions such as oxygen evolution and carbon dioxide formation. Using these on-line MS methods, catalytic water oxidation activity was demonstrated for cis-[Fe(cyclam)Cl2]Cl (1) and [Fe(cyclamacetate)Cl] (2).
