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用于生物成像、传感器、催化和光电子应用的化学掺杂荧光碳量子点和石墨烯量子点。

Chemically doped fluorescent carbon and graphene quantum dots for bioimaging, sensor, catalytic and photoelectronic applications.

作者信息

Du Yan, Guo Shaojun

机构信息

Institute for Cellular and Molecular Biology, Center for Systems and Synthetic Biology, and Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712, USA.

Department of Materials Science and Engineering, & Department of Energy and Resources Engineering, College of Engineering, Peking University, Beijing, 100871, China.

出版信息

Nanoscale. 2016 Feb 7;8(5):2532-43. doi: 10.1039/c5nr07579c.

Abstract

Doping fluorescent carbon dots (DFCDs) with heteroatoms have recently become of great interest compared to traditional fluorescent materials because it provides a feasible and new way to tune the intrinsic properties of carbon quantum dots (CQDs) and graphene quantum dots (GQDs) to achieve new applications for them in different fields. Since the first report on nitrogen (N) doped GQDs in 2012, more effort is being focused on exploring different procedures for making new types of DFCDs with different heteroatoms. This mini review will summarize recent research progress on DFCDs. It first reviews various doping categories achieved up to now, looking back on the synthesis method and comparing the differences in synthesis approaches between the DFCDs and the undoped ones. Then it focuses on the advances on how the doping affects the optical properties, especially DFCDs doped with N, which have been investigated the most. Finally, different applications of DFCDs involving bio-imaging, sensing, catalysis and photoelectronic devices will be discussed. This review will give new insights into how to use different synthetic methods for tuning the structure of DFCDs, understanding the correlation between the doping and properties, and achieving new applications.

摘要

与传统荧光材料相比,掺杂杂原子的荧光碳点(DFCDs)近来备受关注,因为它为调节碳量子点(CQDs)和石墨烯量子点(GQDs)的本征性质提供了一种可行的新方法,从而使它们在不同领域获得新应用。自2012年首次报道氮(N)掺杂的GQDs以来,更多的努力集中在探索制备具有不同杂原子的新型DFCDs的不同方法上。本综述将总结DFCDs的最新研究进展。首先回顾迄今为止实现的各种掺杂类别,回顾合成方法并比较DFCDs与未掺杂碳点合成方法的差异。然后重点关注掺杂如何影响光学性质的进展,尤其是对研究最多的氮掺杂DFCDs。最后,将讨论DFCDs在生物成像、传感、催化和光电器件等方面的不同应用。本综述将为如何使用不同的合成方法调节DFCDs的结构、理解掺杂与性质之间的相关性以及实现新应用提供新的见解。

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