基于离子液体中多组分策略的二氮杂七环笼状体系立体选择性合成的可持续方法。
A Sustainable Approach to the Stereoselective Synthesis of Diazaheptacyclic Cage Systems Based on a Multicomponent Strategy in an Ionic Liquid.
作者信息
Suresh Kumar Raju, Almansour Abdulrahman I, Arumugam Natarajan, Altaf Mohammad, Menéndez José Carlos, Kumar Raju Ranjith, Osman Hasnah
机构信息
Department of Chemistry, College of Science, King Saud University P. O. Box 2455, Riyadh 11451, Saudi Arabia.
Central Laboratory, College of Science, King Saud University P. O. Box 2455, Riyadh 11451, Saudi Arabia.
出版信息
Molecules. 2016 Jan 29;21(2):165. doi: 10.3390/molecules21020165.
The microwave-assisted three-component reactions of 3,5-bis(E)-arylmethylidene]tetrahydro-4(1H)-pyridinones, acenaphthenequinone and cyclic α-amino acids in an ionic liquid, 1-butyl-3-methylimidazolium bromide, occurred through a domino sequence affording structurally intriguing diazaheptacyclic cage-like compounds in excellent yields.
在离子液体1-丁基-3-甲基咪唑溴盐中，3,5-双（E）-芳基亚甲基]四氢-4（1H）-吡啶酮、苊醌和环状α-氨基酸的微波辅助三组分反应通过多米诺序列进行，以优异的产率得到结构有趣的二氮杂七环笼状化合物。
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