Santoro Orlando, Lazreg Faïma, Cordes David B, Slawin Alexandra M Z, Cazin Catherine S J
EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST, UK.
Dalton Trans. 2016 Mar 28;45(12):4970-3. doi: 10.1039/c6dt00595k.
Homo- and heteroleptic bis-NHC copper(I) complexes have been efficiently used as carbene transfer reagents to Au and Pd. The simple and straightforward procedure allows for the synthesis of well-known gold complexes as well as novel cationic bis-NHC Pd(II) species.
均配和杂配双氮杂环卡宾铜(I)配合物已被有效地用作向金和钯转移卡宾的试剂。这种简单直接的方法可用于合成著名的金配合物以及新型阳离子双氮杂环卡宾钯(II)物种。