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连续流动光化学在有机合成、材料科学和水处理中的应用。

Applications of Continuous-Flow Photochemistry in Organic Synthesis, Material Science, and Water Treatment.

机构信息

Department of Chemical Engineering and Chemistry, Micro Flow Chemistry and Process Technology, Eindhoven University of Technology , Den Dolech 2, 5600 MB Eindhoven, The Netherlands.

Department of Organic Chemistry, Ghent University , Krijgslaan 281 (S4), 9000 Ghent, Belgium.

出版信息

Chem Rev. 2016 Sep 14;116(17):10276-341. doi: 10.1021/acs.chemrev.5b00707. Epub 2016 Mar 3.

DOI:10.1021/acs.chemrev.5b00707
PMID:26935706
Abstract

Continuous-flow photochemistry in microreactors receives a lot of attention from researchers in academia and industry as this technology provides reduced reaction times, higher selectivities, straightforward scalability, and the possibility to safely use hazardous intermediates and gaseous reactants. In this review, an up-to-date overview is given of photochemical transformations in continuous-flow reactors, including applications in organic synthesis, material science, and water treatment. In addition, the advantages of continuous-flow photochemistry are pointed out and a thorough comparison with batch processing is presented.

摘要

连续流光化学在微反应器中受到学术界和工业界研究人员的广泛关注,因为这项技术可以缩短反应时间、提高选择性、实现简单的可扩展性,并且可以安全地使用危险中间体和气体反应物。在这篇综述中,对连续流反应器中的光化学反应进行了最新的概述,包括在有机合成、材料科学和水处理中的应用。此外,还指出了连续流光化学的优点,并与间歇处理进行了全面比较。

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