使用基于纳米级Co3O4的催化剂通过可持续的有氧氧化从胺合成腈。
Synthesis of nitriles from amines using nanoscale Co3O4-based catalysts via sustainable aerobic oxidation.
作者信息
Natte Kishore, Jagadeesh Rajenahally V, Sharif Muhammad, Neumann Helfried, Beller Matthias
机构信息
Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany.
出版信息
Org Biomol Chem. 2016 Apr 7;14(13):3356-9. doi: 10.1039/c6ob00184j. Epub 2016 Mar 11.
PMID:26964665
Abstract
The selective oxidation of amines for the benign synthesis of nitriles under mild conditions is described. Key to success for this transformation is the application of reusable cobalt oxide-based nanocatalysts. The resulting nitriles constitute key precursors and central intermediates in organic synthesis.
摘要
描述了在温和条件下通过胺的选择性氧化来良性合成腈的方法。这种转化成功的关键在于应用可重复使用的氧化钴基纳米催化剂。所得的腈是有机合成中的关键前体和核心中间体。
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