Gadge Sandip T, Gautam Prashant, Bhanage Bhalchandra M
Department of Chemistry, Institute of Chemical Technology N. P. Marg, Matunga, Mumbai 400019, India.
Chem Rec. 2016 Apr;16(2):835-56. doi: 10.1002/tcr.201500280. Epub 2016 Mar 10.
In this article, we present the progress made in the area of carbonylative C-H functionalization, with special emphasis on arenes and alkanes. The importance of directing group assistance and C-H functionalization using CO surrogates is also included. The budding development in the area of transition metal-catalyzed C(sp(3))-H activation makes us feel it necessary to file a summary on the past, as well as current, contributions and a prospective outlook on the transition metal-catalyzed carbonylative transformation of C-H bonds, which is the focus of this review.
在本文中,我们介绍了羰基化C-H官能团化领域取得的进展,特别着重于芳烃和烷烃。还包括导向基团辅助以及使用CO替代物进行C-H官能团化的重要性。过渡金属催化的C(sp(3))-H活化领域的蓬勃发展使我们感到有必要对过去以及当前的贡献进行总结,并对过渡金属催化的C-H键羰基化转化进行前瞻性展望,这也是本综述的重点。