Guo Jing, Wang Qingsong, Qi Chao, Jin Jun, Zhu Yingjie, Wen Zhaoyin
CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, P. R. China.
Chem Commun (Camb). 2016 Apr 25;52(32):5613-6. doi: 10.1039/c6cc00638h.
A core-shell structured selenium@carbon composite material was obtained by a facile one-step microwave synthesis method. The uniform carbon shells coated on selenium spheres greatly minimized the shuttle effect of Li-Se cells. The morphology analysis of the cathodes after different cycles revealed that the Se cores were perfectly confined inside the unbroken C shells all through the 100 cycles.
通过简便的一步微波合成法制备了一种核壳结构的硒@碳复合材料。包覆在硒球上的均匀碳壳极大地降低了锂硒电池的穿梭效应。对不同循环次数后的阴极进行形貌分析表明，在整个100次循环中，硒核完美地限制在完整的碳壳内部。
