钯催化氧化条件下由芳基硼酸构建脒类化合物
Palladium-Catalyzed Construction of Amidines from Arylboronic Acids under Oxidative Conditions.
作者信息
Zhu Fengxiang, Li Yahui, Wang Zechao, Orru Romano V A, Maes Bert U W, Wu Xiao-Feng
机构信息
Leibniz-Institut für Katalyse e.V. an der, Universität Rostock, Albert-Einstein-Strasse 29a, 18059, Rostock, Germany.
Department of Chemistry and Pharmaceutical Sciences and Amsterdam, Institute for Molecules, Medicines and Systems (AIMMS), VU University, Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands.
出版信息
Chemistry. 2016 Jun 1;22(23):7743-6. doi: 10.1002/chem.201601262. Epub 2016 Apr 27.
A valuable palladium-catalyzed three-component coupling reaction for the synthesis of amidines has been developed. Using arylboronic acids, isocyanides, and anilines as the reactants under oxidative conditions, various amidines were isolated in good yields with good functional group tolerances.
已开发出一种用于合成脒的有价值的钯催化三组分偶联反应。在氧化条件下，使用芳基硼酸、异腈和苯胺作为反应物，以良好的收率分离得到了各种脒，且官能团耐受性良好。
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