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中国东部长江三角洲不同土地利用类型土壤中重金属的析因克里格分析及来源

Factorial Kriging analysis and sources of heavy metals in soils of different land-use types in the Yangtze River Delta of Eastern China.

作者信息

Zhou Jie, Feng Ke, Li Yinju, Zhou Yang

机构信息

College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, China.

College of Environmental Science and Engineering, Yangzhou University, Yangzhou, 225008, China.

出版信息

Environ Sci Pollut Res Int. 2016 Aug;23(15):14957-67. doi: 10.1007/s11356-016-6619-z. Epub 2016 Apr 14.

Abstract

The objectives of this study are to analyse the pollution status and spatial correlation of soil heavy metals and identify natural and anthropogenic sources of these heavy metals at different spatial scales. Two hundred and twenty-four soil samples (0-20 cm) were collected and analysed for eight heavy metals (Cd, Hg, As, Cu, Pb, Cr, Zn and Ni) in soils of different land-use types in the Yangtze River Delta of Eastern China. The multivariate methods and factorial Kriging analysis were used to achieve the research objectives. The results indicated that the human and natural effects of different land-use types on the contents of soil heavy metals were different. The Cd, Hg, Cu, Pb and Zn in soils of industrial area were affected by human activities, and the pollution level of these heavy metals in this area was moderate. The Pb in soils of traffic area was affected by human activities, and eight heavy metals in soils of residential area and farmland area were affected by natural factor. The ecological risk status of eight heavy metals in soils of the whole study area was light. The heavy metals in soils showed three spatial scales (nugget effect, short range and long range). At the nugget effect and short range scales, the Cd, Hg, Cu, Pb and Zn in soils were affected by human and natural factors. At three spatial scales, the As, Cr and Ni in soils were affected by soil parent materials.

摘要

本研究的目的是分析土壤重金属的污染状况和空间相关性,并在不同空间尺度上确定这些重金属的自然和人为来源。在中国东部长江三角洲地区,采集了224个不同土地利用类型土壤的表层(0 - 20厘米)样品,分析了其中8种重金属(镉、汞、砷、铜、铅、铬、锌和镍)的含量。采用多元统计方法和因子克里金分析来实现研究目标。结果表明,不同土地利用类型对土壤重金属含量的人为和自然影响不同。工业区土壤中的镉、汞、铜、铅和锌受人类活动影响,该区域这些重金属的污染程度为中等。交通区土壤中的铅受人类活动影响,居民区和农田区土壤中的8种重金属受自然因素影响。整个研究区域土壤中8种重金属的生态风险状况为轻度。土壤中的重金属呈现出三种空间尺度(块金效应、短程和长程)。在块金效应和短程尺度上,土壤中的镉、汞、铜、铅和锌受人为和自然因素影响。在三种空间尺度上,土壤中的砷、铬和镍受土壤母质影响。

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