9,10-双（三烷氧基苯乙烯基）蒽衍生物的压致荧光变色和聚集诱导发光性质
Piezoflurochromism and Aggregation Induced Emission Properties of 9, 10-bis (trisalkoxystyryl) Anthracene Derivatives.
作者信息
Duraimurugan Kumaraguru, Sivamani Jayaraman, Sathiyaraj Munusamy, Thiagarajan Viruthachalam, Siva Ayyanar
机构信息
School of Chemistry, Madurai Kamaraj University, Madurai, Tamilnadu, 625 021, India.
School of Chemistry, Bharathidasan University, Trichirapalli-24, Tamilnadu, India.
出版信息
J Fluoresc. 2016 Jul;26(4):1211-8. doi: 10.1007/s10895-016-1805-4. Epub 2016 Apr 15.
We report the synthesis of trisalkoxy substituted 9, 10-bis styrylanthracene derivatives (C8-ant and C12-ant) by Heck coupling with very good yield and their photophysical properties. Both C8-ant and C12-ant exhibit aggregation induced emission (AIE), mechnoflurochromism and thermochromism. Trisubstituted 9, 10-distyrylanthracene molecules having all the luminescent properties in a single molecule are first of its kind.
我们报道了通过Heck偶联以非常高的产率合成三烷氧基取代的9,10-双苯乙烯基蒽衍生物（C8-ant和C12-ant）及其光物理性质。C8-ant和C12-ant均表现出聚集诱导发光（AIE）、机械荧光变色和热致变色。具有所有发光特性的三取代9,10-二苯乙烯基蒽分子在同类分子中尚属首例。
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