铁催化的立体定义的烯醇氨基甲酸酯与格氏试剂的立体选择性交叉偶联反应。
Iron-Catalyzed Stereoselective Cross-Coupling Reactions of Stereodefined Enol Carbamates with Grignard Reagents.
机构信息
Department of Chemistry, The University of Texas at San Antonio, San Antonio, TX, 78249, USA.
出版信息
Angew Chem Int Ed Engl. 2016 Jun 1;55(23):6689-93. doi: 10.1002/anie.201601899. Epub 2016 Apr 18.
PMID:27088754
Abstract
A practical and highly stereoselective iron-catalyzed cross-coupling reaction of stereodefined enol carbamates and Grignard reagents to yield tri- and tetrasubstituted acrylates is reported. A facile method for the stereoselective generation of these enol carbamates has also been developed.
摘要
报道了一种实用且高度对映选择性的铁催化立体定义的烯醇碳酸酯与格氏试剂的交叉偶联反应，以生成三取代和四取代的丙烯酸酯。还开发了一种用于这些烯醇碳酸酯的对映选择性生成的简便方法。
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