Departamento de Química Inorgánica (Módulo 7), Facultad de Ciencias, Universidad Autónoma de Madrid, 28049-Madrid, Spain.
Departamento de Química Orgánica (Módulo 1), Facultad de Ciencias, Universidad Autónoma de Madrid, 28049-Madrid, Spain.
Chem Commun (Camb). 2016 Jul 12;52(58):9137-40. doi: 10.1039/c6cc02452a.
A new catalytic system for the photooxidation of sulfides based on Pt(ii) complexes is presented. The catalyst is capable of oxidizing a large number of sulfides containing aryl, alkyl, allyl, benzyl, as well as more complex structures such as heterocycles and methionine amino acid, with complete chemoselectivity. In addition, the first sulfur oxidation in a continuous flow process has been developed.
本文提出了一种基于 Pt(ii) 配合物的新型用于硫化物光氧化的催化体系。该催化剂能够氧化含有芳基、烷基、烯丙基、苄基以及更复杂结构如杂环和蛋氨酸氨基酸的大量硫化物，具有完全的化学选择性。此外，还开发了第一个在连续流动过程中的硫氧化。
