通过金（I）催化的环化异构化反应合成（-）-大麻酚酮和大麻酚酮的结构重排。
Synthesis of (-)-Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)-Catalyzed Cycloisomerization.
机构信息
Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007, Tarragona, Spain.
Departament de Química Analítica i Química, Orgànica, Universitat Rovira i Virgili, C/ Marcel⋅li Domingo s/n, 43007, Tarragona, Spain.
出版信息
Angew Chem Int Ed Engl. 2016 Jun 13;55(25):7121-5. doi: 10.1002/anie.201601834. Epub 2016 Apr 27.
Abstract
The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)-catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.
摘要
大麻酚酮的首次全合成及其来自于大麻的无水大麻酚酮是通过高度立体选择性的金（I）催化环化异构化反应来实现的。研究结果导致无水大麻酚酮的结构重新分配。
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