由双核和九核铁分子配合物催化的水氧化反应：合适配体框架的重要性。
Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework.
作者信息
Das Biswanath, Lee Bao-Lin, Karlsson Erik A, Åkermark Torbjörn, Shatskiy Andrey, Demeshko Serhiy, Liao Rong-Zhen, Laine Tanja M, Haukka Matti, Zeglio Erica, Abdel-Magied Ahmed F, Siegbahn Per E M, Meyer Franc, Kärkäs Markus D, Johnston Eric V, Nordlander Ebbe, Åkermark Björn
机构信息
Inorganic Chemistry Research Group, Chemical Physics, Center for Chemistry and Chemical Engineering, Lund University, PO Box 124, SE-22100 Lund, Sweden.
出版信息
Dalton Trans. 2016 Sep 14;45(34):13289-93. doi: 10.1039/c6dt01554a. Epub 2016 Jun 6.
The synthesis of two molecular iron complexes, a dinuclear iron(iii,iii) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant Ru(bpy)3.
描述了基于双核配体2,2'-(2-羟基-5-甲基-1,3-亚苯基)双(1H-苯并[d]咪唑-4-羧酸)合成的两种分子铁配合物，一种双核铁(III,III)配合物和一种九核铁配合物。发现这两种铁配合物能通过单电子氧化剂Ru(bpy)₃驱动水的氧化反应。
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