Das Biswanath, Lee Bao-Lin, Karlsson Erik A, Åkermark Torbjörn, Shatskiy Andrey, Demeshko Serhiy, Liao Rong-Zhen, Laine Tanja M, Haukka Matti, Zeglio Erica, Abdel-Magied Ahmed F, Siegbahn Per E M, Meyer Franc, Kärkäs Markus D, Johnston Eric V, Nordlander Ebbe, Åkermark Björn
Inorganic Chemistry Research Group, Chemical Physics, Center for Chemistry and Chemical Engineering, Lund University, PO Box 124, SE-22100 Lund, Sweden.
Dalton Trans. 2016 Sep 14;45(34):13289-93. doi: 10.1039/c6dt01554a. Epub 2016 Jun 6.
The synthesis of two molecular iron complexes, a dinuclear iron(iii,iii) complex and a nonanuclear iron complex, based on the dinucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant Ru(bpy)3.
描述了基于双核配体2,2'-(2-羟基-5-甲基-1,3-亚苯基)双(1H-苯并[d]咪唑-4-羧酸)合成的两种分子铁配合物，一种双核铁(III,III)配合物和一种九核铁配合物。发现这两种铁配合物能通过单电子氧化剂Ru(bpy)₃驱动水的氧化反应。
