可见光促进的无金属条件下肉桂酸与磺酰基腙的脱羧磺酰化反应。
Visible-Light-Enabled Decarboxylative Sulfonylation of Cinnamic Acids with Sulfonylhydrazides under Transition-Metal-Free Conditions.
机构信息
Key Laboratory of Modern Analytical Science and Separation Technology of Fujian Province, School of Chemistry and Environment, Minnan Normal University , Zhangzhou 363000, China.
Key Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Shenzhen Graduate School, Peking University , Shenzhen 518055, China.
出版信息
Org Lett. 2016 Jun 17;18(12):2990-3. doi: 10.1021/acs.orglett.6b01353. Epub 2016 Jun 7.
Decarboxylative cross-coupling reactions of cinnamic acids with sulfonylhydrazides were explored using oxygen as the sole terminal oxidant, realizing a conceptually novel technology for vinyl sulfone synthesis under the synergistic interactions of visible light irradiation, organic dye-type photocatalyst eosin Y, KI, and Cs2CO3 at room temperature.
探索了肉桂酸与磺酰基腙的脱羧交叉偶联反应，以氧气作为唯一的终端氧化剂，在可见光照射、有机染料型光催化剂曙红 Y、KI 和 Cs2CO3 的协同作用下，在室温下实现了一种用于乙烯基砜合成的新概念技术。
Zotero 插件