电子供体-受体络合物实现肉桂酸在可见光照射下的脱羧磺酰化反应。
Electron Donor-Acceptor Complex Enabled Decarboxylative Sulfonylation of Cinnamic Acids under Visible-Light Irradiation.
作者信息
Ge Qian-Qian, Qian Jia-Sheng, Xuan Jun
机构信息
Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, College of Chemistry & Chemical Engineering , Anhui University , Hefei , Anhui 230601 , People's Republic of China.
Institute of Physical Science and Information Technology , Anhui University , Hefei , Anhui 230601 , People's Republic of China.
出版信息
J Org Chem. 2019 Jul 5;84(13):8691-8701. doi: 10.1021/acs.joc.9b00552. Epub 2019 Jun 14.
Visible-light-induced decarboxylative sulfonylation of cinnamic acids with aryl sulfonate phenol esters enabled by the electron donor-acceptor complex is developed. The method offers a mild and green approach for the synthesis of vinyl sulfones with excellent functional group compatibility under photocatalyst and oxidant-free conditions.
开发了一种通过电子给体-受体络合物实现的可见光诱导肉桂酸与芳基磺酸酚酯的脱羧磺酰化反应。该方法为在无光催化剂和氧化剂条件下合成具有优异官能团兼容性的乙烯基砜提供了一种温和且绿色的途径。
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