Medalion Shlomi, Aghion Erez, Meirovitch Hagai, Barkai Eli, Kessler David A
Department of Physics, Bar-Ilan University, Ramat-Gan, 52900, Israel.
Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan, 52900, Israel.
Sci Rep. 2016 Jun 15;6:27661. doi: 10.1038/srep27661.
We present an exact solution for the distribution of sample averaged monomer to monomer distance of ring polymers. For non-interacting and local-interaction models these distributions correspond to the distribution of the area under the reflected Bessel bridge and the Bessel excursion respectively, and are shown to be identical in dimension d ≥ 2, albeit with pronounced finite size effects at the critical dimension, d = 2. A symmetry of the problem reveals that dimension d and 4 - d are equivalent, thus the celebrated Airy distribution describing the areal distribution of the d = 1 Brownian excursion describes also a polymer in three dimensions. For a self-avoiding polymer in dimension d we find numerically that the fluctuations of the scaled averaged distance are nearly identical in dimension d = 2, 3 and are well described to a first approximation by the non-interacting excursion model in dimension 5.
我们给出了环状聚合物样本平均单体到单体距离分布的精确解。对于非相互作用和局部相互作用模型,这些分布分别对应于反射贝塞尔桥和贝塞尔游程下面积的分布,并且在维度(d\geq2)时显示为相同,尽管在临界维度(d = 2)处存在明显的有限尺寸效应。问题的对称性表明维度(d)和(4 - d)是等价的,因此描述(d = 1)布朗游程面积分布的著名艾里分布也描述了三维聚合物。对于维度(d)中的自回避聚合物,我们通过数值发现,标度平均距离的涨落在维度(d = 2)、(3)时几乎相同,并且在维度(5)中,非相互作用游程模型能很好地对其进行一阶近似描述。