Ulusoy Şafak, Özden Özkan, Päpke Olaf
Faculty of Fisheries, Department of Seafood Processing Technology and Safety, Istanbul University, Ordu st. No: 200, 34134, Laleli, Fatih, Istanbul, Turkey.
Eurofins -ERGO Research, Neuländer Kamp 1, 21079, Hamburg, Germany.
Bull Environ Contam Toxicol. 2016 Aug;97(2):191-7. doi: 10.1007/s00128-016-1848-x. Epub 2016 Jun 21.
Mussel samples were collected monthly between October-2010 and October-2011 from four stations (Bosphorus, Bandırma, Gelibolu, Tekirdağ) in the Marmara Sea. Two consecutive months' samples were homogenized and combined as a single group for analysis. Mussel samples were analyzed for Organochlorine pesticides (OCPs); (total-DDT, total-HCH, Endrin, α-Endosulfan, β-Endosulfan, Heptachlor) and Polychlorinated biphenyls (PCBs); (PCB 28, PCB 52, PCB 138, PCB 153, and PCB 180). All analyses were done according to Eurofins house method in ERGO Laboratory in Germany. Concentrations of α-endosulfan and heptachlor in mussel tissues were below method detection limits. The annual average OCPs concentrations among the stations ranged between 0.02 and 1.45 ng/g (wet weight), 1.9-99.75 ng/g (lipid weight) whereas the annual average PCBs concentrations among the stations ranged between 0.03 and 0.40 ng/g (wet weight), 1.71-26.48 ng/g (lipid weight), respectively. There was no relation between fat content of mussels and residues of the contaminants. PCB 138 and PCB 153 were the most predominant PCBs, while total-DDT and total-HCH were the most predominant OCPs in the mussels. Total-DDT concentrations were higher compared to total-HCH and PCBs isomers. Measured levels were below the national and international committees' and institutions' limits for human consumption and protection of aquatic biota.
2010年10月至2011年10月期间,每月从马尔马拉海的四个站点(博斯普鲁斯海峡、班德尔马、盖利博卢、泰基尔达)采集贻贝样本。将连续两个月的样本进行均质化处理并合并为一组进行分析。对贻贝样本进行有机氯农药(OCPs)分析;(总滴滴涕、总六氯环己烷、异狄氏剂、α-硫丹、β-硫丹、七氯)和多氯联苯(PCBs)分析;(多氯联苯28、多氯联苯52、多氯联苯138、多氯联苯153和多氯联苯180)。所有分析均按照德国ERGO实验室的欧陆科技集团内部方法进行。贻贝组织中α-硫丹和七氯的浓度低于方法检测限。各站点的有机氯农药年平均浓度在0.02至1.45纳克/克(湿重)之间,1.9至99.75纳克/克(脂重)之间,而各站点的多氯联苯年平均浓度分别在0.03至0.40纳克/克(湿重)之间,1.71至26.48纳克/克(脂重)之间。贻贝的脂肪含量与污染物残留之间没有关系。多氯联苯138和多氯联苯153是贻贝中最主要的多氯联苯,而总滴滴涕和总六氯环己烷是贻贝中最主要的有机氯农药。总滴滴涕浓度高于总六氯环己烷和多氯联苯异构体。测量水平低于国家和国际委员会及机构规定的人类消费和保护水生生物群的限值。