Department of Chemistry, Indiana University, 800 E Kirkwood Ave., Bloomington, IN 47405, USA.
Chem Commun (Camb). 2016 Jul 5;52(56):8683-6. doi: 10.1039/c6cc03463b.
The size-dependent recognition of large anions by shape-persistent macrocycles is poorly understood. To address this shortcoming, we created a bulky cyanostar that only forms 1 : 1 complexes and show the affinities best follow the expectations of size matching but only when solvent bias is removed.
大离子的尺寸依赖识别作用被形状固定的大环化合物所忽视。为了解决这一缺点，我们创造了一个庞大的氰星，它只形成 1：1 的配合物，并且显示出亲和力最好遵循尺寸匹配的预期，但只有当溶剂偏差被消除时才是这样。
