液态镍 - 锡 - 锌合金的混合焓

The Enthalpies of Mixing of Liquid Ni-Sn-Zn Alloys.

作者信息

Plevachuk Yu, Yakymovych A, Fürtauer S, Ipser H, Flandorfer H

机构信息

Department of Metal Physics, Ivan Franko National University, Kyrylo and Mephodiy Str. 8, Lviv, 79005 Ukraine.

Department of Inorganic Chemistry (Materials Chemistry), University of Vienna, Währinger Str. 42, 1090 Wien, Austria.

出版信息

J Phase Equilibria Diffus. 2014;35(4):359-368. doi: 10.1007/s11669-014-0288-8. Epub 2014 Feb 22.

DOI:10.1007/s11669-014-0288-8

PMID:27335535

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4894259/

Abstract

The partial and integral enthalpies of mixing of liquid ternary Ni-Sn-Zn alloys were determined. The system was investigated along two sections / ≈ 1:9, / ≈ 1:6 at 1073 K and along two sections / ≈ 9:1, / ≈ 4:1 at 873 K. The integral enthalpy of mixing at each temperature is described using the Redlich-Kister-Muggianu model for substitutional ternary solutions. In addition, the experimental results were compared with data calculated according to the Toop extrapolation model. The minimum integral enthalpy of approx. -20000 J mol corresponds to the minimum in the constituent binary Ni-Sn system, the maximum of approx. 3000 J mol is equal to the maximum in the binary Sn-Zn system.

摘要

测定了液态三元Ni-Sn-Zn合金的混合偏焓和混合积分焓。在1073K下沿两条截面/≈1:9、/≈1:6对该体系进行了研究，在873K下沿两条截面/≈9:1、/≈4:1进行了研究。每个温度下的混合积分焓用替代三元溶液的Redlich-Kister-Muggianu模型进行描述。此外，还将实验结果与根据Toop外推模型计算的数据进行了比较。约-20000J/mol的最小混合积分焓对应于二元Ni-Sn体系中的最小值，约3000J/mol的最大值等于二元Sn-Zn体系中的最大值。