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使用星状活性炭和芬顿试剂处理自助洗衣店废水

Treatment of laundrette wastewater using Starbon and Fenton's reagent.

作者信息

Tony Maha A, Parker Helen L, Clark James H

机构信息

a Green Chemistry Centre of Excellence, Department of Chemistry, University of York , York , UK.

b Basic Engineering Science Department , Faculty of Engineering, Minoufiya University , Shbin El-Koum , Egypt.

出版信息

J Environ Sci Health A Tox Hazard Subst Environ Eng. 2016 Sep 18;51(11):974-9. doi: 10.1080/10934529.2016.1191817. Epub 2016 Jun 23.

Abstract

The use of grey water for a variety of purposes is gaining increased popularity as a means of preserving scarce freshwater resources. In this work, catalytic oxidation over Fenton's reagent and adsorption techniques using Starbon (mesoporous material derived from polysaccharides) has been applied. These novel techniques are used as an alternative to already studied treatments of grey water such as filtration and/or biological processes. In this study, grey water, collected from a commercial laundrette, has been used. Treatment efficiency was determined by changes in the chemical oxygen demand (COD) of the grey water. Experiments using Fenton's reagent at optimum conditions of Fe(3+) = 40 mg L(-1); H2O2 = 400 mg L(-1) and pH 3 were very successful, resulting in a 95% COD removal after 15 min. Treatment with Starbon adsorption was also effective, reaching up to 81% COD removal at pH 3 within 1 h. The combined treatment with Fenton's reagent and Starbon resulted in a 93% COD removal at a significantly reduced concentration of Fenton's reagent compared to the treatment with solo Fenton's reagent. This lower chemical dose has the advantage of reducing costs and lowering sludge generation.

摘要

将中水用于多种用途作为一种保护稀缺淡水资源的手段正越来越受欢迎。在这项工作中,采用了在芬顿试剂上的催化氧化以及使用Starbon(一种由多糖衍生的介孔材料)的吸附技术。这些新技术被用作已研究的中水的处理方法(如过滤和/或生物处理)的替代方法。在本研究中,使用了从一家商业洗衣店收集的中水。处理效率通过中水的化学需氧量(COD)的变化来确定。在Fe(3+) = 40 mg L(-1);H2O2 = 400 mg L(-1)和pH 3的最佳条件下使用芬顿试剂进行的实验非常成功,15分钟后COD去除率达到95%。用Starbon吸附处理也很有效,在pH 3时1小时内COD去除率高达81%。与单独使用芬顿试剂处理相比,芬顿试剂和Starbon联合处理在芬顿试剂浓度显著降低的情况下COD去除率达到93%。这种较低的化学剂量具有降低成本和减少污泥产生的优点。

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