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基于取向氧化锌纳米棒的安培型非酶过氧化氢传感器。

Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods.

作者信息

Al-Hardan Naif H, Abdul Hamid Muhammad Azmi, Shamsudin Roslinda, Othman Norinsan Kamil, Kar Keng Lim

机构信息

School of Applied Physics, Faculty of Science & Technology, Universiti Kebangsaan Malaysia (UKM), Bangi 43600, Malaysia.

出版信息

Sensors (Basel). 2016 Jun 29;16(7):1004. doi: 10.3390/s16071004.

DOI:10.3390/s16071004
PMID:27367693
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4970054/
Abstract

Zinc oxide (ZnO) nanorods (NRs) have been synthesized via the hydrothermal process. The NRs were grown over a conductive glass substrate. A non-enzymatic electrochemical sensor for hydrogen peroxide (H₂O₂), based on the prepared ZnO NRs, was examined through the use of current-voltage measurements. The measured currents, as a function of H₂O₂ concentrations ranging from 10 μM to 700 μM, revealed two distinct behaviours and good performance, with a lower detection limit (LOD) of 42 μM for the low range of H₂O₂ concentrations (first region), and a LOD of 143.5 μM for the higher range of H₂O₂ concentrations (second region). The prepared ZnO NRs show excellent electrocatalytic activity. This enables a measurable and stable output current. The results were correlated with the oxidation process of the H₂O₂ and revealed a good performance for the ZnO NR non-enzymatic H₂O₂ sensor.

摘要

通过水热法合成了氧化锌(ZnO)纳米棒(NRs)。这些纳米棒生长在导电玻璃基板上。基于制备的ZnO纳米棒,通过电流-电压测量对一种用于过氧化氢(H₂O₂)的非酶电化学传感器进行了检测。测量的电流作为H₂O₂浓度(范围从10 μM到700 μM)的函数,显示出两种不同的行为和良好的性能,对于低浓度范围的H₂O₂(第一区域),检测限(LOD)为42 μM,对于高浓度范围的H₂O₂(第二区域),检测限为143.5 μM。制备的ZnO纳米棒表现出优异的电催化活性。这使得能够产生可测量且稳定的输出电流。结果与H₂O₂的氧化过程相关,并显示出ZnO纳米棒非酶H₂O₂传感器具有良好的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/61ead508f05a/sensors-16-01004-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/543572b2ce4f/sensors-16-01004-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/efc3efc924ae/sensors-16-01004-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/436d882b9414/sensors-16-01004-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/61ead508f05a/sensors-16-01004-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/543572b2ce4f/sensors-16-01004-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/efc3efc924ae/sensors-16-01004-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/436d882b9414/sensors-16-01004-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c113/4970054/61ead508f05a/sensors-16-01004-g004.jpg

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