Kamamoto Yu, Nitta Yuya, Kubo Kazuyuki, Mizuta Tsutomu, Kume Shoko
Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan.
Chem Commun (Camb). 2016 Aug 18;52(69):10486-9. doi: 10.1039/c6cc03407a.
Two types of redox functionality were selected for covalent immobilization on a carbon electrode, using an electric potential as the sole stimulus. A redox-active copper catalyst transformed a terminal alkyne in two ways with and without an oxidation process, to form a triazole or butadiyne.
