用于光催化水析氢的扩展共轭微孔聚合物
Extended conjugated microporous polymers for photocatalytic hydrogen evolution from water.
作者信息
Sprick Reiner Sebastian, Bonillo Baltasar, Sachs Michael, Clowes Rob, Durrant James R, Adams Dave J, Cooper Andrew I
机构信息
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool, L69 7ZD, UK.
Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ, UK.
出版信息
Chem Commun (Camb). 2016 Aug 4;52(65):10008-11. doi: 10.1039/c6cc03536a.
Conjugated microporous polymers (CMPs) have been used as photocatalysts for hydrogen production from water in the presence of a sacrificial electron donor. The relative importance of the linker geometry, the co-monomer linker length, and the degree of planarisation were studied with respect to the photocatalytic hydrogen evolution rate.
共轭微孔聚合物（CMPs）已被用作光催化剂，在牺牲电子供体存在的情况下从水中制氢。研究了连接基几何结构、共聚单体连接基长度和平面化程度对光催化析氢速率的相对重要性。
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