School of Chemistry & Biochemistry, Georgia Institute of Technology , 901 Atlantic Drive NW, Atlanta, Georgia 30332, United States.
Department of Chemistry, University of Washington , Seattle, Washington 98195, United States.
Chem Rev. 2016 Aug 10;116(15):8318-72. doi: 10.1021/acs.chemrev.6b00366. Epub 2016 Jul 25.
Hydride complexes of copper, silver, and gold encompass a broad array of structures, and their distinctive reactivity has enabled dramatic recent advances in synthesis and catalysis. This Review summarizes the synthesis, characterization, and key stoichiometric reactions of isolable or observable coinage metal hydrides. It discusses catalytic processes in which coinage metal hydrides are known or probable intermediates, and presents mechanistic studies of selected catalytic reactions. The purpose of this Review is to convey how developments in coinage metal hydride chemistry have led to new organic transformations, and how developments in catalysis have in turn inspired the synthesis of reactive new complexes.
铜、银和金的氢化物配合物包含广泛的结构，其独特的反应性使得在合成和催化方面取得了显著的进展。本文综述了可分离或可观察到的金银铜氢化物的合成、表征和关键计量反应。讨论了已知或可能是中间产物的金银铜氢化物的催化过程，并介绍了一些选定催化反应的机理研究。本文的目的是说明金银铜氢化物化学的发展如何导致了新的有机转化，以及催化的发展如何反过来激发了新的反应性配合物的合成。
