苯乙烯作为 Zn(II)催化的分子间 Diels-Alder/ene 串联反应的 4π-组分。
Styrene as 4π-Component in Zn(II)-Catalyzed Intermolecular Diels-Alder/Ene Tandem Reaction.
机构信息
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology , Guangzhou, 510640, P. R. China.
出版信息
Org Lett. 2016 Aug 5;18(15):3554-7. doi: 10.1021/acs.orglett.6b01511. Epub 2016 Jul 26.
PMID:27458734
Abstract
A mild Zn-catalyzed intermolecular Diels-Alder/ene tandem reaction with styrene as a 4π-component is reported. A variety of dihydronaphthalene products could be prepared in moderate to good yields. Moreover, a combination of DFT calculations and experiments was performed to further understand the mechanism of this unique tandem reaction.
摘要
报道了一种温和的 Zn 催化的 Diels-Alder/ene 串联反应，其中苯乙烯作为 4π 组分。可以中等至良好的收率制备各种二氢萘产物。此外，还进行了 DFT 计算和实验的组合，以进一步了解这种独特的串联反应的机理。
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