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离子液体对层状磷酸锆纳米片的小分子辅助剥离

Small Molecule-Assisted Exfoliation of Layered Zirconium Phosphate Nanoplatelets by Ionic Liquids.

作者信息

Xia Fangqing, Yong Huaisong, Han Xiao, Sun Dazhi

机构信息

Department of Materials Science and Engineering, South University of Science and Technology of China, Shenzhen, 518055, Guangdong Province, China.

Shenzhen Key Laboratory of Nanoimprint Technology, South University of Science and Technology of China, Shenzhen, 518055, Guangdong Province, China.

出版信息

Nanoscale Res Lett. 2016 Dec;11(1):348. doi: 10.1186/s11671-016-1559-6. Epub 2016 Jul 27.

DOI:10.1186/s11671-016-1559-6
PMID:27460596
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4961662/
Abstract

Exfoliation of layered inorganic nanomaterials into single-layered sheets has been widely interested in materials chemistry and composite fabrication. Here, we report the exfoliation of layered zirconium phosphate nanoplatelets by using small molecule intercalating agents in ionic liquids, which opens a new platform for fabricating single-layered inorganic materials from synthetic layered compounds.

摘要

将层状无机纳米材料剥离成单层薄片已在材料化学和复合材料制备领域引起广泛关注。在此,我们报道了在离子液体中使用小分子插层剂对层状磷酸锆纳米片进行剥离,这为从合成层状化合物制备单层无机材料开辟了一个新平台。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/91f34d18a8a8/11671_2016_1559_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/7514c68002a0/11671_2016_1559_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/104764e5180d/11671_2016_1559_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/f461e64e1501/11671_2016_1559_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/4491ddbf4490/11671_2016_1559_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/91f34d18a8a8/11671_2016_1559_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/7514c68002a0/11671_2016_1559_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/104764e5180d/11671_2016_1559_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/f461e64e1501/11671_2016_1559_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/4491ddbf4490/11671_2016_1559_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fee5/4961662/91f34d18a8a8/11671_2016_1559_Fig5_HTML.jpg

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本文引用的文献

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The Rapid Exfoliation and Subsequent Restacking of Layered Titanates Driven by an Acid-Base Reaction.酸堿反应驱动的层状钛酸盐的快速剥离和随后的重堆积。
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Sulfonic acid-functionalized α-zirconium phosphate single-layer nanosheets as a strong solid acid for heterogeneous catalysis applications.磺酸功能化磷酸锆单层纳米片作为用于多相催化应用的强固体酸
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