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大脉冲电子束焊接银纳米线的渗透网络,用于透明和灵活的电极。

Large Pulsed Electron Beam Welded Percolation Networks of Silver Nanowires for Transparent and Flexible Electrodes.

机构信息

School of Mechanical and Nuclear Engineering and ‡School of Materials Science and Engineering and KIST-UNIST Ulsan Center for Convergent Materials, Ulsan National Institute of Science and Technology (UNIST) , UNIST-gil 50, Eonyang-eup, Ulju-gun, Ulsan, Republic of Korea , 44919.

出版信息

ACS Appl Mater Interfaces. 2016 Aug 17;8(32):20938-45. doi: 10.1021/acsami.6b05874. Epub 2016 Aug 5.


DOI:10.1021/acsami.6b05874
PMID:27463783
Abstract

Mechanical properties of transparent electrodes, including flexibility, are important in flexible electronics for sustaining electrical conductivity under bending with small radius of curvature. Low contact resistance of junctions in metal nanowire percolation networks is the most important factor to produce electrodes with excellent optical, electrical and mechanical performance. Here, we report the fabrication of welded silver nanowire percolation networks using large pulsed electron beam (LPEB) irradiation as a welding process of silver nanowires (AgNWs). It results in modification of electrical and mechanical properties because of the low contact resistance at welded junctions. Consequently, the flexible and transparent AgNW electrodes fabricated by LPEB irradiation showed lower sheet resistance of 12.63 Ω sq(-1) at high transmittance of 93% (at 550 nm), and superb mechanical flexibility, compared with other AgNW electrodes prepared by thermal treatement and without any treatment. Polymer light-emitting diodes (PLEDs) using AgNWs by LPEB irradiation were fabricated to confirm that the AgNW electrode by LPEB irradiation was able to become alternative to indium tin oxide (ITO) and they showed good device performance as a maximum luminous efficiency of 7.37 cd A(-1), and excellent mechanical flexibility under bending with small radius of curvature.

摘要

透明电极的机械性能,包括柔韧性,在柔性电子中非常重要,因为它们需要在小曲率半径的弯曲下保持电导率。金属纳米线渗流网络中结的低接触电阻是产生具有优异光学、电学和机械性能的电极的最重要因素。在这里,我们报告了使用大脉冲电子束(LPEB)辐照作为银纳米线(AgNWs)的焊接工艺来制造焊接银纳米线渗流网络。这导致了焊接结处的低接触电阻,从而改变了电和机械性能。因此,通过 LPEB 辐照制备的柔性透明 AgNW 电极在高透光率(550nm 时为 93%)下表现出较低的方阻(12.63 Ω sq(-1)),以及出色的机械柔韧性,与通过热处理和无任何处理制备的其他 AgNW 电极相比。使用 LPEB 辐照的 AgNW 制备了聚合物发光二极管(PLEDs),以证实通过 LPEB 辐照的 AgNW 电极能够替代铟锡氧化物(ITO),并且它们在小曲率半径的弯曲下表现出良好的器件性能,最大发光效率为 7.37 cd A(-1),以及出色的机械柔韧性。

相似文献

[1]
Large Pulsed Electron Beam Welded Percolation Networks of Silver Nanowires for Transparent and Flexible Electrodes.

ACS Appl Mater Interfaces. 2016-8-5

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[10]
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[4]
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