Chuan Tan Ying, Chun Zeng Hua
Department of Chemical and Biomolecular Engineering, Faculty of Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 119260.
Chem Commun (Camb). 2016 Oct 4;52(77):11591-4. doi: 10.1039/c6cc05699g. Epub 2016 Sep 7.
An aqueous one-pot self-templating synthesis method to prepare highly uniform ZIF-67 hollow spheres (ZIF-67-HS) and their transition metal-doped derivatives (M/ZIF-67-HS, M = Cu and/or Zn) was developed. Extension of this approach to another important class of MOFs (metal carboxylates; e.g., HKUST-1) and facile design of derived nanostructures with complex architectures were also achieved.
开发了一种水相一锅自模板合成方法，用于制备高度均匀的ZIF-67空心球（ZIF-67-HS）及其过渡金属掺杂衍生物（M/ZIF-67-HS，M = Cu和/或Zn）。该方法还扩展到另一类重要的金属有机框架（金属羧酸盐，例如HKUST-1），并实现了具有复杂结构的衍生纳米结构的简便设计。
