Frequency-Driven Self-Organized Helical Superstructures Loaded with Mesogen-Grafted Silica Nanoparticles.

Adding colloidal nanoparticles into liquid-crystal media has become a promising pathway either to enhance or to introduce novel properties for improved device performance. Here we designed and synthesized new colloidal hybrid silica nanoparticles passivated with a mesogenic monolayer on the surface to facilitate their organo-solubility and compatibility in a liquid-crystal host. The resulting nanoparticles were identified by H NMR spectroscopy, TEM, TGA, and UV/Vis techniques, and the hybrid nanoparticles were doped into a dual-frequency cholesteric liquid-crystal host to appraise both their compatibility with the host and the effect of the doping concentration on their electro-optical properties. Interestingly, the silica-nanoparticle-doped liquid-crystalline nanocomposites were found to be able to dynamically self-organize into a helical configuration and exhibit multi-stability, that is, homeotropic (transparent), focal conic (opaque), and planar states (partially transparent), depending on the frequency applied at sustained low voltage. Significantly, a higher contrast ratio between the transparent state and scattering state was accomplished in the nanoparticle-embedded liquid-crystal systems.