Department of Chemistry and the Macromolecular and Engineering Programm, University of Michigan, 930 North University Avenue, Ann Arbor, MI, 48109-1055, USA.
Angew Chem Int Ed Engl. 2016 Oct 10;55(42):13118-13121. doi: 10.1002/anie.201607130.
Two polymorphic hydrogen peroxide solvates of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20; wurtzitane is an alternative name to iceane) were obtained using hydrated α-CL-20 as a guide. These novel H O solvates have high crystallographic densities (1.96 and 2.03 g cm , respectively), high predicted detonation velocities/pressures (with one solvate performing better than ϵ-CL-20), and a sensitivity similar to that of ϵ-CL-20. The use of hydrated materials as a guide will be important in the development of other energetic materials with hydrogen peroxide. These solvates represent an area of energetic materials that has yet to be explored.
两种 2,4,6,8,10,12-六硝-2,4,6,8,1 0,12-六氮杂异伍兹烷（CL-20；伍兹烷是冰烷的另一种名称）的多晶态过氧化氢溶剂合物是使用水合的α-CL-20 作为指导获得的。这些新型的 H2O 溶剂合物具有高的晶体密度（分别为 1.96 和 2.03 g/cm3）、高预测爆轰速度/压力（一种溶剂合物的性能优于 ε-CL-20）以及与 ε-CL-20 相似的敏感度。使用水合材料作为指导对于开发其他具有过氧化氢的高能材料将是重要的。这些溶剂合物代表了一个尚未开发的高能材料领域。
