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高浓度还原氧化石墨烯增强铜具有仿生纳米层状结构和较大的可恢复变形能力。

High content reduced graphene oxide reinforced copper with a bioinspired nano-laminated structure and large recoverable deformation ability.

机构信息

State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, China.

出版信息

Sci Rep. 2016 Sep 20;6:33801. doi: 10.1038/srep33801.

Abstract

By using CuO/graphene-oxide/CuO sandwich-like nanosheets as the building blocks, bulk nacre-inspired copper matrix nano-laminated composite reinforced by molecular-level dispersed and ordered reduced graphene oxide (rGO) with content as high as ∼45 vol% was fabricated via a combined process of assembly, reduction and consolidation. Thanks to nanoconfinement effect, reinforcing effect, as well as architecture effect, the nanocomposite shows increased specific strength and at least one order of magnitude greater recoverable deformation ability as compared with monolithic Cu matrix.

摘要

采用 CuO/氧化石墨烯/CuO 三明治状纳米片作为构建块,通过组装、还原和固结的组合工艺,制备了高达约 45 体积%的分子水平分散和有序还原氧化石墨烯(rGO)增强的块状珍珠层启发的铜基纳米层压复合纳米复合材料。由于纳米约束效应、增强效应以及结构效应,与整体 Cu 基体相比,纳米复合材料表现出更高的比强度和至少一个数量级更大的可恢复变形能力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d801/5029288/af954c76c4ca/srep33801-f1.jpg

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