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一种形状定制的金导电聚合物纳米复合材料,用作对挥发性有机化合物(VOCs)具有非凡不敏感性的透明电极。

A shape tailored gold-conductive polymer nanocomposite as a transparent electrode with extraordinary insensitivity to volatile organic compounds (VOCs).

作者信息

Khalil Rania, Homaeigohar Shahin, Häußler Dietrich, Elbahri Mady

机构信息

Nanochemistry and Nanoengineering, Faculty of Engineering, University of Kiel, Institute for Materials Science, Kaiserstrasse 2, 24143 Kiel, Germany.

Physics Department, Faculty of Science, Zagazig University 44519, Zagazig, Egypt.

出版信息

Sci Rep. 2016 Sep 22;6:33895. doi: 10.1038/srep33895.

Abstract

In this study, the transparent conducting polymer of poly (3,4-ethylenendioxythiophene): poly(styrene sulphonate) (PEDOT:PSS) was nanohybridized via inclusion of gold nanofillers including nanospheres (NSs) and nanorods (NRs). Such nanocomposite thin films offer not only more optimum conductivity than the pristine polymer but also excellent resistivity against volatile organic compounds (VOCs). Interestingly, such amazing properties are achieved in the diluted regimes of the nanofillers and depend on the characteristics of the interfacial region of the polymer and nanofillers, i.e. the aspect ratio of the latter component. Accordingly, a shape dependent response is made that is more desirable in case of using the Au nanorods with a much larger aspect ratio than their nanosphere counterparts. This transparent nanocomposite thin film with an optimized conductivity and very low sensitivity to organic gases is undoubtedly a promising candidate material for the touch screen panel production industry. Considering PEDOT as a known material for integrated electrodes in energy saving applications, we believe that our strategy might be an important progress in the field.

摘要

在本研究中,聚(3,4 - 亚乙基二氧噻吩):聚(苯乙烯磺酸盐)(PEDOT:PSS)这种透明导电聚合物通过包含金纳米填料(包括纳米球(NSs)和纳米棒(NRs))进行了纳米杂化。这种纳米复合薄膜不仅比原始聚合物具有更优的导电性,而且对挥发性有机化合物(VOCs)具有出色的抗性。有趣的是,这些惊人的特性是在纳米填料的稀释体系中实现的,并且取决于聚合物和纳米填料界面区域的特性,即后者的长径比。因此,形成了一种形状依赖性响应,在使用长径比远大于纳米球的金纳米棒时这种响应更理想。这种具有优化导电性且对有机气体敏感度极低的透明纳米复合薄膜无疑是触摸屏面板生产行业一种很有前景的候选材料。考虑到PEDOT是节能应用中集成电极的一种已知材料,我们相信我们的策略可能是该领域的一项重要进展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63d4/5032166/42e18f3c3499/srep33895-f1.jpg

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