Erten Edibe S, Cadwallader Keith R
Department of Food Science and Human Nutrition, University of Illinois at Urbana-Champaign, 1302 W Pennsylvania Ave, 61801 Urbana, IL, USA.
Food Chem. 2017 Feb 15;217:244-253. doi: 10.1016/j.foodchem.2016.08.091. Epub 2016 Aug 26.
Volatile components of raw, dry roasted and oil roasted almonds were isolated by solvent extraction/solvent-assisted flavor evaporation and predominant aroma compounds identified by gas chromatography-olfactometry (GCO) and aroma extract dilutions analysis (AEDA). Selected odorants were quantitated by GC-mass spectrometry and odor-activity values (OAVs) determined. Results of AEDA indicated that 1-octen-3-one and acetic acid were important aroma compounds in raw almonds. Those predominant in dry roasted almonds were methional, 2- and 3-methylbutanal, 2-acetyl-1-pyrroline and 2,3-pentanedione; whereas, in oil roasted almonds 4-hydroxy-2,5-dimethyl-3(2H)-furanone, 2,3-pentanedione, methional and 2-acetyl-1-pyrroline were the predominant aroma compounds. Overall, oil roasted almonds contained a greater number and higher abundance of aroma compounds than either raw or dry roasted almonds. The results of this study demonstrate the importance of lipid-derived volatile compounds in raw almond aroma. Meanwhile, in dry and oil roasted almonds, the predominant aroma compounds were derived via the Maillard reaction, lipid degradation/oxidation and sugar degradation.
通过溶剂萃取/溶剂辅助风味蒸发法分离生杏仁、干烤杏仁和油烤杏仁中的挥发性成分,并通过气相色谱-嗅觉测定法(GCO)和香气提取物稀释分析(AEDA)鉴定主要的香气化合物。通过气相色谱-质谱法定量选定的气味物质,并确定气味活性值(OAV)。AEDA结果表明,1-辛烯-3-酮和乙酸是生杏仁中的重要香气化合物。干烤杏仁中的主要成分是甲硫醛、2-和3-甲基丁醛、2-乙酰基-1-吡咯啉和2,3-戊二酮;而在油烤杏仁中,4-羟基-2,5-二甲基-3(2H)-呋喃酮、2,3-戊二酮、甲硫醛和2-乙酰基-1-吡咯啉是主要的香气化合物。总体而言,油烤杏仁中香气化合物的数量和丰度均高于生杏仁或干烤杏仁。本研究结果证明了脂质衍生的挥发性化合物在生杏仁香气中的重要性。同时,在干烤和油烤杏仁中,主要的香气化合物是通过美拉德反应、脂质降解/氧化和糖降解产生的。