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苯烷基胺钝化有机卤化铅钙钛矿,实现高效率和空气稳定的光伏电池。

Phenylalkylamine Passivation of Organolead Halide Perovskites Enabling High-Efficiency and Air-Stable Photovoltaic Cells.

机构信息

Department of Electronic Engineering, The Chinese University of Hong Kong, New Territories, Hong Kong.

Beijing Computational Science Research Center, Beijing, 100084, P. R. China.

出版信息

Adv Mater. 2016 Dec;28(45):9986-9992. doi: 10.1002/adma.201603062. Epub 2016 Sep 28.

DOI:10.1002/adma.201603062
PMID:27677653
Abstract

Benzylamine is introduced as a surface passivation molecule that improves the moisture-resistance of the perovskites while simultaneously enhancing their electronic properties. Solar cells based on benzylamine-modified formamidinium lead iodide perovskite films exhibit a champion efficiency of 19.2% and an open-circuit voltage of 1.12 V. The modified FAPbI films exhibit no degradation after >2800 h air exposure.

摘要

苯甲胺被引入作为一种表面钝化分子,可提高钙钛矿的耐湿性,同时提高其电子性能。基于苯甲胺修饰的甲脒碘化铅钙钛矿薄膜的太阳能电池表现出 19.2%的冠军效率和 1.12 V 的开路电压。修饰后的 FAPbI 薄膜在 >2800 h 的空气暴露后没有降解。

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