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通过温州蜜柑（Citrus unshiu Marc.）花蜜/蜜囊/蜂蜜顶空、挥发物和半挥发物途径追踪其蜂蜜：化学标志物

Traceability of Satsuma Mandarin (Citrus unshiu Marc.) Honey through Nectar/Honey-Sac/Honey Pathways of the Headspace, Volatiles, and Semi-Volatiles: Chemical Markers.

作者信息

Jerković Igor, Prđun Saša, Marijanović Zvonimir, Zekić Marina, Bubalo Dragan, Svečnjak Lidija, Tuberoso Carlo I G

机构信息

Department of Organic Chemistry, Faculty of Chemistry & Technology, University of Split, Ruđera Boškovića 35, HR-21000 Split, Croatia.

Department of Fisheries, Apiculture and Special Zoology, Faculty of Agriculture, University of Zagreb, Svetošimunska 25, HR-10000 Zagreb, Croatia.

出版信息

Molecules. 2016 Sep 29;21(10):1302. doi: 10.3390/molecules21101302.

DOI:10.3390/molecules21101302
PMID:27689986
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6273672/
Abstract

Headspace solid-phase microextraction (HS-SPME) and ultrasonic solvent extraction (USE), followed by GC-MS/FID, were applied for monitoring the nectar (NE)/honey-sac (HoS)/honey (HO) pathways of the headspace, volatiles, and semi-volatiles. The major NE (4 varieties of ) headspace compounds were linalool, α-terpineol, 1-indole, methyl anthranilate, and phenylacetonitrile. Corresponding extracts contained, among others, 1-indole, methyl anthranilate, 1,3-dihydro-2-indol-2-one and caffeine. The major HoS headspace compounds were linalool, α-terpineol, 1,8-cineole, 1-indole, methyl anthranilate, and -jasmone. Characteristic compounds from HoS extract were caffeine, 1-indole, 1,3-dihydro-2-indol-2-one, methyl anthranilate, and phenylacetonitrile. However, HO headspace composition was significantly different in comparison to NE and HoS with respect to phenylacetaldehyde and linalool derivatives abundance that appeared as the consequence of the hive conditions and the bee enzyme activity. honey traceability is determined by chemical markers: phenylacetaldehyde, phenylacetonitrile, linalool and its derivatives, as well as 1-indole, 1,3-dihydro-2-indol-2-one, and caffeine.

摘要

顶空固相微萃取（HS-SPME）和超声溶剂萃取（USE），随后采用气相色谱-质谱联用/火焰离子化检测（GC-MS/FID），用于监测花蜜（NE）/蜜囊（HoS）/蜂蜜（HO）顶空、挥发性成分和半挥发性成分的路径。主要的NE（4个品种的）顶空化合物为芳樟醇、α-松油醇、1-吲哚、邻氨基苯甲酸甲酯和苯乙腈。相应的提取物除其他成分外，还含有1-吲哚、邻氨基苯甲酸甲酯、1,3-二氢-2-吲哚-2-酮和咖啡因。主要的HoS顶空化合物为芳樟醇、α-松油醇、1,8-桉叶素、1-吲哚、邻氨基苯甲酸甲酯和茉莉酮。HoS提取物的特征性化合物为咖啡因、1-吲哚、1,3-二氢-2-吲哚-2-酮、邻氨基苯甲酸甲酯和苯乙腈。然而，HO的顶空成分与NE和HoS相比，在苯乙醛和芳樟醇衍生物的丰度方面存在显著差异，这是蜂巢条件和蜜蜂酶活性的结果。蜂蜜的可追溯性由化学标志物决定：苯乙醛、苯乙腈、芳樟醇及其衍生物，以及1-吲哚、1,3-二氢-2-吲哚-2-酮和咖啡因。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f27/6273672/16bb77b1e428/molecules-21-01302-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f27/6273672/6ced9b64cc90/molecules-21-01302-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f27/6273672/16bb77b1e428/molecules-21-01302-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f27/6273672/6ced9b64cc90/molecules-21-01302-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f27/6273672/16bb77b1e428/molecules-21-01302-g002.jpg

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