Shiraishi H, Carter D S, Hites R A
School of Public and Environmental Affairs, Indiana University, Bloomington 47405.
Biomed Environ Mass Spectrom. 1989 Jul;18(7):478-83. doi: 10.1002/bms.1200180706.
Whole carp from the Detroit River were analyzed by gas chromatographic mass spectrometry. Seven tertiary alkyl phenols (tert-pentylphenols, tert-butyl-tert-pentylphenols, a di-tert-pentylphenol and a tri-tert-pentylphenol) and eight chlorinated derivatives of these compounds were identified from their mass spectra and confirmed with synthesized authentic standards. 2,4-Di-tert-pentylphenol was the most abundant of these compounds; in one fish sample, its concentration was about 140 ppm. The same alkyl phenols were also found in technical-grade 2,4-di-tert-pentylphenol, which is manufactured at a chemical plant located near the Detroit River. Comparison of the alkyl phenol levels in carp with those in nearby sediments showed that many of these compounds are taken up by carp and that carp can be used to roughly track local sediment contamination.
采用气相色谱-质谱联用仪对底特律河的整条鲤鱼进行了分析。从质谱图中鉴定出了七种叔烷基酚（叔戊基酚、叔丁基-叔戊基酚、一种二叔戊基酚和一种三叔戊基酚）及其八种氯化衍生物，并用合成的标准品进行了确认。2,4-二叔戊基酚是这些化合物中含量最高的；在一份鱼类样本中，其浓度约为140 ppm。在位于底特律河附近的一家化工厂生产的工业级2,4-二叔戊基酚中也发现了同样的烷基酚。将鲤鱼体内的烷基酚水平与附近沉积物中的烷基酚水平进行比较后发现，鲤鱼会摄取许多这类化合物，并且鲤鱼可用于大致追踪当地沉积物的污染情况。
