Beckman Institute, California Institute of Technology , Pasadena, California 91125, United States.
Chem Rev. 2017 Jul 12;117(13):8483-8496. doi: 10.1021/acs.chemrev.6b00583. Epub 2016 Oct 21.
Recent developments in C-H bond activation and functionalization by Pt complexes are surveyed. Topics include the following: fundamental mechanistic investigations of C-H activation; stoichiometric intra- and intermolecular C-H activation; reactions of dioxygen with Pt(II) complexes that may be relevant to substrate oxygenation; and both stoichiometric and catalytic formation of C-O, C-C, and C-B bonds via C-H activation. Current interests and trends are discussed, both in the context of historical work and to forecast future directions and opportunities for the field.
综述了近年来铂配合物引发的 C-H 键活化及功能化反应的最新进展。内容包括：C-H 键活化的基本反应机理；C-H 键的计量内、分子间活化；可能与底物氧化相关的 Pt(II)配合物与氧气的反应；以及通过 C-H 键活化实现 C-O、C-C 和 C-B 键的形成（包括计量和催化过程）。本文在讨论当前的研究热点和趋势时，既回顾了该领域的历史发展，也展望了未来的方向和机遇。
